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Synthesis of poly(vinyl acetate)-b-poly(4-vinylpyridine) block copolymers by a combination of cobalt-mediated radical polymerization and RAFT polymerization and their use in dispersion polymerization under UV radiation

✍ Scribed by Hyun Jeong Jeon; Young Chang Yu; Ji Ho Youk


Book ID
113039292
Publisher
Springer
Year
2012
Weight
861 KB
Volume
290
Category
Article
ISSN
0340-255X

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## Abstract A novel block copolymer, poly(ε‐caprolactone)‐__b__‐poly(4‐vinyl pyridine), was synthesized with a bifunctional initiator strategy. Poly(ε‐caprolactone) prepolymer with a 2,2,6,6‐tetramethylpiperidinyloxy (TEMPO) end group (PCL~T~) was first obtained by coordination polymerization, whic