In spite of containing three conformationally accessible Ξ²-H atoms, palladacycle 1βa is an isolable intermediate in the asymmetric Heck cyclization of 2βa. Although 1βa is stable in the presence of the hydrotriflate salt of 1,2,2,6,6-pentamethylpiperidine, it is converted into the oxindole Heck prod
β¦ LIBER β¦
Synthesis of Novel Tetracycles via an Intramolecular Heck Reaction with anti-Hydride Elimination.
β Scribed by Mark Lautens; Yuan-Qing Fang
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 151 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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