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Synthesis of novel metal complexes of the 1,2-dithiolene ligand, 1,2,5-thiadiazole-3,4-dithiol: precursors to new molecular conductors

✍ Scribed by Hawkins, Ian; Underhill, Allan E.


Book ID
118160205
Publisher
The Royal Society of Chemistry
Year
1990
Tongue
English
Weight
145 KB
Volume
22
Category
Article
ISSN
0022-4936

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Synthesis and crystal structure of [Bu4N
✍ Yvonne S. J. Veldhuizen; Nora Veldman; Anthony L. Spek; Jaap G. Haasnoot; Jan Re πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 222 KB

## Abstract [Bu~4~N][Ni(mdt)~2~] (H~2~mdt = 2__H__‐1,3‐dithiole‐4,5‐dithiol) has been prepared in a three‐step synthesis from [Bu~4~N]~2~[Zn(dmit)~2~] (H~2~dmit = 2‐thione‐1,3‐dithiole‐4,5‐dithiol). The crystal structure is reported which shows that the Ni(mdt)~2~ anion is distorted significantly f