A practical synthesis of chiral amine precursors 3 and 4 and chiral diaza 18-crown-6 ethers 5, 6 and 7 starting from chiral amines are reported. The molecular recognition of these chiral crown ethers for amino acids potassium and sodium salts has been characterized by UV-vis. The selectivity order i
✦ LIBER ✦
Synthesis of Novel ChiralC2-symmetric Diaza-18-crown-6 Ether Derivatives and their Enantioselective Recognition of Amino Acid Derivatives
✍ Scribed by Yılmaz Turgut; Nadir Demirel; Halil Hoşgören
- Publisher
- Springer Netherlands
- Year
- 2006
- Tongue
- English
- Weight
- 306 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0923-0750
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## Abstract Complexation of amino acids as their sodium and potassium salts by optically active diaza crown ethers has been investigated in transport across bulk liquid membranes containing the carriers and in extraction experiments. The observed enantioselectivity was achieved by (noncovalent) ste
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