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Synthesis of novel chiral phosphinocyrhetrenyloxazoline ligands and their application in asymmetric catalysis

โœ Scribed by Bolm, Carsten; Xiao, Li; Kesselgruber, Martin

Book ID
115536990
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
188 KB
Volume
1
Category
Article
ISSN
1477-0520

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Synthesis of chiral phosphine ligands wi
Synthesis of chiral phosphine ligands with aromatic backbones and their applications in asymmetric catalysis
โœ James M. Longmire; Xumu Zhang ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 204 KB

A general strategy for the synthesis of new chiral phosphine ligands has been discovered. A common feature of these ligands is that they contain rigid aromatic backbones which can be used to restrict conformational flexibility. The bite angle of P-M-P can be changed systematically depending on the