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Synthesis of Chiral Olefin Ligands and their Application in Asymmetric Catalysis

✍ Scribed by Dr. Xiangqing Feng; Prof. Dr. Haifeng Du

Book ID
115549496
Publisher
Wiley (John Wiley & Sons)
Year
2012
Tongue
English
Weight
907 KB
Volume
1
Category
Article
ISSN
2193-5807

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Synthesis of chiral phosphine ligands wi
Synthesis of chiral phosphine ligands with aromatic backbones and their applications in asymmetric catalysis
✍ James M. Longmire; Xumu Zhang 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 204 KB

A general strategy for the synthesis of new chiral phosphine ligands has been discovered. A common feature of these ligands is that they contain rigid aromatic backbones which can be used to restrict conformational flexibility. The bite angle of P-M-P can be changed systematically depending on the