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Synthesis of novel 5a,10,14b,15-tetraaza-benzo[a]indeno[1,2-c]anthracen-5-one and benzimidazo[1,2-c]quinazoline derivatives under microwave irradiation

✍ Scribed by Mustapha Soukri; Gérald Guillaumet; Thierry Besson; Driss Aziane; Mina Aadil; El Mokhtar Essassi; Mohamed Akssira


Book ID
104210621
Publisher
Elsevier Science
Year
2000
Tongue
French
Weight
105 KB
Volume
41
Category
Article
ISSN
0040-4039

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✦ Synopsis


Novel

5a,10,14b,15-tetraaza-benzo[a]

indeno [1,2-c]anthracen-5-one and benzimidazo[1,2-c]quinazoline derivatives were synthesised in good yields in two or three steps from 2-(2-aminophenyl)indole and 2-(2aminophenyl)benzimidazole. Microwave irradiation in homogeneous phase or in dry media was used in order to improve reactions where conventional heating (metal or oil bath) was limited.


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Efficient modified von Niementowski synt
✍ Lisianne Domon; Catherine Le Coeur; Axelle Grelard; Valérie Thiéry; Thierry Bess 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 128 KB

Starting from 2-(2-aminophenyl)indole novel triazabenzo[a]indeno[1,2-c]anthracen-5-ones could be reached in three steps through a modified von Niementowski reaction, which involves condensation of anthranilic acids with an S-alkylated 6-mercaptoindolo[1,2-c]quinazoline. Microwave irradiation in dry