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Synthesis of Nonracemic α-Trifluoromethyl α-Amino Acids from Sulfinimines of Trifluoropyruvate

✍ Scribed by Amparo Asensio; Pierfrancesco Bravo; Marcello Crucianelli; Alessandra Farina; Santos Fustero; Juan García Soler; Stefano V. Meille; Walter Panzeri; Fiorenza Viani; Alessandro Volonterio; Matteo Zanda


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
489 KB
Volume
2001
Category
Article
ISSN
1434-193X

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The fast atom bombardment-induced mass spectrometric behaviour of four Ñuorinated a-amino acids was studied in detail with the aid of metastable ion studies and accurate mass measurements. Comparison with the behaviour of unÑuorinated analogues suggests that the presence of Ñuorine makes the carbony