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Organocatalytic Enantioselective Strecker Synthesis of α-Quaternary α-Trifluoromethyl Amino Acids

✍ Scribed by Dieter Enders; Katharina Gottfried; Gerhard Raabe


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
190 KB
Volume
352
Category
Article
ISSN
1615-4150

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The fast atom bombardment-induced mass spectrometric behaviour of four Ñuorinated a-amino acids was studied in detail with the aid of metastable ion studies and accurate mass measurements. Comparison with the behaviour of unÑuorinated analogues suggests that the presence of Ñuorine makes the carbony