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Synthesis of non-proteinogenic amino acids from N-(4-toluenesulfonyl)dehydroamino acid derivatives

✍ Scribed by Paula M.T. Ferreira; Hernâni L.S. Maia; Luı́s S. Monteiro


Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
174 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


By treating N-(4-toluenesulfonyl)-N-(tert-butyloxycarbonyl)-dehydroamino acid derivatives with different reactants under different conditions, a variety of new amino acids are obtained, viz. (i) a-alcoxy-a-amino acids, (ii) a,a-diamino acids and (iii) novel b-substituted dehydroamino acids.


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