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Non-proteinogenic amino acid synthesis. The β-anion derived from aspartic acid, and its application to α-amino acid synthesis.

✍ Scribed by Jack E. Baldwin; Mark G. Moloney; Michael North

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
899 KB
Volume
45
Category
Article
ISSN
0040-4020

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✦ Synopsis

Treatment of a-t-Butyl B-methyl fi-Z-(S)-aspartate (2) with lithium amide bases generates the corresponding g-ester enolate , which can be alkylated

📜 SIMILAR VOLUMES

Non-proteinogenic amino acid synthesis:
Non-proteinogenic amino acid synthesis: Synthesis of β,γ-unsaturated α-amino acids from asparic acid
✍ Jack E Baldwin; Mark G Moloney; Michael North 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 609 KB

A general, stereospecific, synthesis of S,Y-unsaturated a-amino acids using the S-anion derived from aspartic acid is described . S,Y-Unsaturated amino acids have been found to be reversible or irreversible inhibitors of a number of enzymes,' and this has prompted a number of racemic syntheses of th

ChemInform Abstract: Synthesis of Amino
ChemInform Abstract: Synthesis of Amino Acids and Related Compounds. Part 49. Stereoselective Synthesis of β-Benzyl-α-alkyl-β-amino Acids from L-Aspartic Acid.
✍ Masahiko Seki; Toshiaki Shimizu; Kazuo Matsumoto 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 37 KB 👁 2 views

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