SYNTHESIS OF NITROXYL DERIVATIVES OF BENZO[a]PYRENE
✍ Scribed by Schlude, H.
- Book ID
- 120564608
- Publisher
- Taylor and Francis Group
- Year
- 1977
- Tongue
- English
- Weight
- 307 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0030-4948
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## Abstract The synthesis of benzo[a]pyrene‐6‐^13^C is described. Perinaphthane was converted to 6‐benzoyl‐carbonyl‐^13^C‐perinaphthane which was cyclized to 2,3‐dihydrobenzo[a]pyren‐6(1H)‐one‐6‐^13^C. Subsequent reduction of the ketone followed by dehydration and dehydrogenation gave benzo[a]pyren
## Abstract 6‐Lithiobenzo[__a__]pyrene was carbonated to produce benzo[__a__]pyrene‐6‐carboxylic‐^14^C acid, which was in turn used in the preparation of several derivatives. Methylation to the ester was followed by LiAlH~4~ reduction to 6‐hydroxymethyl‐^14^C‐benzo[__a__]pyrene. An efficient oxidat