Synthesis of Nitrones Using the Methyltrioxorhenium/Hydrogen Peroxide System
โ Scribed by Murray, Robert W.; Iyanar, Kaliappan; Chen, Jianxin; Wearing, James T.
- Book ID
- 120219551
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 111 KB
- Volume
- 61
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Some secondary amines of varying structural type have been oxidized by the methyltrioxorhenium/hydrogen peroxide system to the corresponding nitroxides in excellent yield. These results, coupled with our earlier work using this system, indicate the striking parallel between this chemistry and that o
Methyltrioxorhenium catalyzes the oxidation of C6o by hydrogen peroxide to give C6oO. The reaction continues to produce C6oO2 and higher oxides. The yield of C6oO represents a modest improvement over that given by other methods. The reaction conditions can be manipulated to give high conversions of