Oxidation of [60]fullerene by the methyltrioxorhenium-hydrogen peroxide system
β Scribed by Robert W. Murray; Kaliappan Iyanar
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 192 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Methyltrioxorhenium catalyzes the oxidation of C6o by hydrogen peroxide to give C6oO. The reaction continues to produce C6oO2 and higher oxides. The yield of C6oO represents a modest improvement over that given by other methods. The reaction conditions can be manipulated to give high conversions of the Ceo.
π SIMILAR VOLUMES
Baeyer-Villiger reaction / Lactones / Methyltrioxorhenium / Catalysis / Oxidations / Cyclobutanones / Ketones Ξ³-Butyrolactones were obtained in good yields and high rings, and chlorine substituents. A trimethylsiloxysubstituted ketone was converted directly into a hydro-regioselectivity by a Baeyer-
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