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Synthesis of new triarylphosphine ligand and their application in styrene hydroformylation

✍ Scribed by Yu Guo; Haiyan Fu; Hua Chen; Xianjun Li

Book ID: 119216340
Publisher: Elsevier Science
Year: 2008
Tongue: English
Weight: 168 KB
Volume: 9
Category: Article
ISSN: 1566-7367
DOI: 10.1016/j.catcom.2008.02.017

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## Abstract The synthesis of calix[4]arene‐based phosphorus diamides and phosphites is described. These oligocyclic ligands have been tested in the Rh(I)‐ catalyzed hydroformylation of 1‐octene. Depending on the reaction conditions, yields up to 99% and __n/iso__‐selectivities between 0.7 and 2.6 h