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Synthesis of new chiral phosphine–phosphites and diphosphites and their application in asymmetric hydroformylation

✍ Scribed by V Beghetto; A Scrivanti; U Matteoli


Book ID
118629703
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
83 KB
Volume
2
Category
Article
ISSN
1566-7367

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Synthesis of new chiral monodentate phos
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A general synthesis of chiral 4,5-dihydro-3H-dinaphthophosphepines 1a-g is described. The resulting ligands represent a new class of monodentate chiral phosphines. First applications of 1a-g in the rhodium-catalyzed asymmetric hydrogenation of unsaturated carboxylic acid derivatives demonstrate the