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Synthesis of New Silylated Sulfur-Containing Heterocycles Through Thionation of Bis(acylsilanes).

✍ Scribed by Jean-Philippe Bouillon; Antonella Capperucci; Charles Portella; Alessandro Degl'Innocenti


Publisher
John Wiley and Sons
Year
2004
Weight
110 KB
Volume
35
Category
Article
ISSN
0931-7597

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Synthesis of Sulfur-Containing Large-Membered Heterocycles (Crown Thioethers) with Bis(o-mercapto)phenyl Sulfide. -Bis(omercaptophenyl) sulfide reacts with 1,2-dibromoethane, 1,3-dibromopropane, and cis-1,2-dichloroethylene to give the thioethers (I)-(III). -(NAKAYAMA,