ChemInform Abstract: Synthesis of Sulfur-Containing Large-Membered Heterocycles (Crown Thioethers) with Bis(o-mercapto)phenyl Sulfide.

✍ Scribed by Juzo Nakayama; Ayako Kaneko; Yoshiaki Sugihara; Akihiko Ishii

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 29 KB
• Volume: 30
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199949151

✦ Synopsis

Synthesis of Sulfur-Containing Large-Membered Heterocycles (Crown Thioethers) with Bis(o-mercapto)phenyl Sulfide.

-Bis(omercaptophenyl) sulfide reacts with 1,2-dibromoethane, 1,3-dibromopropane, and cis-1,2-dichloroethylene to give the thioethers (I)-(III). -(NAKAYAMA,