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Synthesis of new semi-rigid chelating agents for samarium-153

โœ Scribed by Anthony Loussouarn; Ali Ouadi; Laurence Morandeau; Patricia Remaud; Robin Giles; Jean-Francois Gestin; John Webb

Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
169 KB
Volume
44
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

This study describes a simple, efficient synthesis pathway from trans-1,2-diaminocyclohexane that provides access to a new class of semi-rigid polyamine, polycarboxylic, and polyphosphonic ligands. The key steps in synthesis were the functionalisation (with an appropriate branching group) of a bisphosphonate diaminocyclohexane derivative and the introduction of methanephosphonic functions by a rarely used method.

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Synthesis of new potential chelating agents: Catecholโ€“bisphosphonate conjugates for metal intoxication therapy
โœ Guangyu Xu; Chunhao Yang; Bo Liu; Xihan Wu; Yuyuan Xie ๐Ÿ“‚ Article ๐Ÿ“… 2004 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 107 KB ๐Ÿ‘ 1 views

## Abstract In a quest for better chelating therapy drugs for the treatment of intoxication by Fe, Al, or actinides, three new series of bisphosphonates conjugated with catechol were synthesized. ยฉ 2004 Wiley Periodicals, Inc. Heteroatom Chem 15:251โ€“257, 2004; Published online in Wiley InterScience