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Synthesis of new polymers containing α-(trifluoromethyl)-acrylate units

✍ Scribed by Mauro Aglietto; Elisa Passaglia; Lorenzo Montagnini di Mirabello; Carlo Botteghi; Stefano Paganelli; Ugo Matteoli; Gloria Menchi

Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
463 KB
Volume
196
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

Free radical polymerization of both α‐(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4‐tert‐butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TFMAA with α‐olefins (1‐decene, 2‐methyl‐1‐hexene) and of methyl α‐(trifluoromethyl)acrylate (MTFMA) with vinyl ethers (butyl, 2‐ethylhexyl, and menthyl vinyl ether) can be simply obtained with AIBN as initiator; these copolymers have a predominantly alternating structure.

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