Poly[(methylsilylene)ethynylene] (1) and poly[2,5-thiophenediyl(methylsilylene)] (2) are prepared in good yields. Thermogravimetric analysis and differential scanning calorimetry indicate the Si-H group to increase the pyrolysis residue yields. Gelation was achieved from polymer 1 to get improved pr
Synthesis of new polymers containing tannin
β Scribed by Min Kim; Kyoichi Saito; Shintaro Furusaki; Takanobu Sugo; Jiro Okamoto
- Publisher
- John Wiley and Sons
- Year
- 1990
- Tongue
- English
- Weight
- 654 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0021-8995
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β¦ Synopsis
A novel method for preparation of immobilized tannin on polyethylene has been suggested. A tannin-containing polymer was prepared by radiation-induced graft polymerization of glycidyl methacrylate onto porous polyethylene, followed by coupling tannin with the produced epoxide group. Reaction conditions for preparing immobilized tannin, such as the reaction temperature, pH, and the molar ratio of tannin to the epoxide group were investigated. The tannin content of the tannin-containing porous polyethylene was 2076, which is approximately equivalent to that of the conventional cellulose-based immobilized tannin. The adsorption isotherm for immobilized tannin and ferrous ion was determined.
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