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Synthesis of New Photoresponsive Polymers Containing Trifluoromethyl-Substituted Norbornadiene Moieties

✍ Scribed by Nagai, Takabumi; Shimada, Miwa; Ono, Yoshitomo; Nishikubo, Tadatomi


Book ID
127327889
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
157 KB
Volume
36
Category
Article
ISSN
0024-9297

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## Abstract Free radical polymerization of both α‐(trifluoromethyl)acrylic acid (TFMAA) and its methyl ester MTFMA is shown to be possible in the presence of bis(4‐__tert__‐butylcyclohexyl) peroxycarbonate (Percadox) as initiator and dioxane or THF as solvent. Also it is shown that copolymers of TF