## Abstract Nucleophilic or radical addition of trimethylsilyl esters of trivalent organophosphorus acids to various functionalized acrylates and their cyclic analogues is proposed as convenient methods for the synthesis of new 2‐trimethylsiloxycarbonyl‐substituted alkylphosphonites and their deriv
✦ LIBER ✦
Synthesis of New 18-Substituted Analogues of Calcitriol Using a Photochemical Remote Functionalization
✍ Scribed by Cornella, Iván; Pérez Sestelo, José; Mouriño, Antonio; Sarandeses, Luis A.
- Book ID
- 121486214
- Publisher
- American Chemical Society
- Year
- 2002
- Tongue
- English
- Weight
- 134 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-3263
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Photolysis of 3-acyl-2-thiotetrahydro-1,3\_thiazines followed by acetylation gave bicyclic B-lactams accompanied by Type II cleavage products. High temperature photolysis of them gave 2,9-dithia-6-azabicyclo[4,3,Olnonan-