Synthesis of N-fluorodinitromethylpyridinium salts as first examples of hitherto unknown class of compounds
β Scribed by V.V. Semenow; A.A. Gakh
- Book ID
- 104150445
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 44 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-1139
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Reaction of either 9, or diphenylethanedione (benzil) with two equivalents of Li[N(SiMe 3 ) 2 ], followed by quenching of the reaction with excess Cl-SiMe 3 , produces the corresponding N,NΠbis(trimethylsilyl)-β£-diimines in high yields (85-95%). Subsequent dehalosilylation/ring-closure reactions wi
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