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Synthesis of myo-inositol 1-phosphate and 4-phosphate, and of their individual enantiomers

✍ Scribed by Billington, David C.; Baker, Raymond; Kulagowski, Janusz J.; Mawer, Ian M.

Book ID
124065736
Publisher
The Royal Society of Chemistry
Year
1987
Tongue
English
Weight
336 KB
Volume
4
Category
Article
ISSN
0022-4936

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## Abstract Synthesis of __LL, DD__ and __LD__ stereoisomers of di‐__myo__‐inositol‐1,1′‐phosphate (DIP) could be realised by phosphitylation of properly protected __L__‐ or __D__‐__myo__‐inositol derivatives. It was also established that naturally occurring (+)‐DIP has the __LL__‐configuration.

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A novel method for synthesis of myo-inositol l-phosphate using phosphorus oxychloride is described an transferred to synthesis of its thiophosphate analogue. ## The inhibition of myo -inositol l-phosphatase UP1 -ase) by lithium ions is used therapeutically in treating manic-depressive illnesses '