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Synthesis of multi-arm star polystyrene with hyperbranched polyester initiators by atom transfer radical polymerization

✍ Scribed by Guohua Jiang; Li Wang; Tao Chen; Chang Chen; Haojie Yu


Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
172 KB
Volume
99
Category
Article
ISSN
0021-8995

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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym