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Polystyrene-block-polylactide obtained by the combination of atom transfer radical polymerization and ring-opening polymerization with a commercial dual initiator

✍ Scribed by Mohammed Dirany; Patrick Lacroix-Desmazes; Marylène Vayer; René Erre; Bernard Boutevin; Christophe Sinturel


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
201 KB
Volume
122
Category
Article
ISSN
0021-8995

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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym