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Synthesis of Modified Weinreb Amides: N-tert-Butoxy-N-methylamides as Effective Acylating Agents.

✍ Scribed by Olivier Labeeuw; Phannarath Phansavath; Jean-Pierre Genet

Publisher: John Wiley and Sons
Year: 2005
Weight: 156 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200502057

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📜 SIMILAR VOLUMES

N-methoxy-n-methylamides as effective ac

N-methoxy-n-methylamides as effective acylating agents

✍ Steven Nahm; Steven M. Weinreb 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 176 KB

Readily preparable N-methoxy-N-methylamides couple in good yields with Grignard and organolithium reagents to produce ketones, and are reduced with hydrides to afford aldehydes.