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Synthesis of Methylene-Bridge Polyarenes through Palladium-Catalyzed Activation of Benzylic Carbon-Hydrogen Bond

โœ Scribed by Chien-Chi Hsiao; Yi-Kuan Lin; Chia-Ju Liu; Tsun-Cheng Wu; Yao-Ting Wu

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
279 KB
Volume
352
Category
Article
ISSN
1615-4150

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## Abstract A novel palladiumโ€catalyzed synthesis of substituted 3โ€methyleneโ€3__H__โ€indoles from readily accessible alkynylimines has been developed. A wide variety of 2โ€fluoroalkylโ€3โ€methyleneโ€3__H__โ€indoles were synthesized in moderate to good yields through this cascade carbopalladation/C๏ฃฟH acti