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Synthesis of (±)-Methyl Epijasmonate and (±)-Methyl Dihydroepijasmonate by Diastereoselective Protonation

✍ Scribed by Norbert Krause; Sophia Ebert


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
253 KB
Volume
2001
Category
Article
ISSN
1434-193X

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ChemInform Abstract: A Convenient Synthe
✍ J. S. U; H. S. PARK; S. GUPTA; J. K. CHA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 2 views

A Convenient Synthesis of (-)-Methyl Epijasmonate. -A short, enantioselective synthesis of the title "isoprostane" (XII) starting from commercially available Corey lactone aldehyde (I) is given. The key features of the sequence are the stereoselective construction of the 2,3-cis-disubstituted cyclo