## Abstract Poly(epichlorohydrin) possessing chloromethyl side groups in the main chain was used in the atom transfer radical polymerization of methyl methacrylate and styrene to yield poly(epichlorohydrin‐__g__‐methyl methacrylate) and poly(epichlorohydrin‐__g__‐styrene graft copolymers. The polym
✦ LIBER ✦
Synthesis of methyl acrylate graft copolymers by the combination of a polynorbornene containing pendant vinylbenzene groups by using coordination and reverse atom transfer polymerization
✍ Scribed by Rui Ma; Zhongying Song; Yubang Hou; Juan Feng; Bin Xing; Feng Bao
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 190 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0268-2605
- DOI
- 10.1002/aoc.1399
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## Abstract The kinetics and controllability of the Ti[OCH~2~CCl~3~]~4~‐initiated atom transfer radical polymerization (ATRP) of __n__‐butyl acrylate were investigated. Then, with Ti[OCH~2~CCl~3~]~4~ as the initiator, poly(ϵ‐caprolactone)‐__block__‐poly(__n__‐butyl acrylate) (PCL‐__b__‐PBA) copolym