## Abstract Poly(epichlorohydrin‐__g__‐styrene) and poly (epichlorohydrin‐__g__‐methyl methacrylate) graft copolymers were synthesized by a combination of cationic and photoinitiated free‐radical polymerization. For this purpose, first, epichlorohydrin was polymerized with tetrafluoroboric acid (HB
Synthesis of poly(epichlorohydrin-g-methyl methacrylate) graft copolymers by the combination of cationic and atom transfer radical polymerization
✍ Scribed by Ismail Cakmak; Haci Baykara
- Publisher
- John Wiley and Sons
- Year
- 2006
- Tongue
- English
- Weight
- 269 KB
- Volume
- 102
- Category
- Article
- ISSN
- 0021-8995
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✦ Synopsis
Abstract
Poly(epichlorohydrin) possessing chloromethyl side groups in the main chain was used in the atom transfer radical polymerization of methyl methacrylate and styrene to yield poly(epichlorohydrin‐g‐methyl methacrylate) and poly(epichlorohydrin‐g‐styrene graft copolymers. The polymers were characterized by ^1^H NMR spectroscopy, gel permeation chromatography, differential scanning calorimetry, and fractional precipitation method. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 2725–2729, 2006
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