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Synthesis of methyl acetate from methanol catalyzed by [(η5-C5H5)(phosphine)2RuX] and [(η5-C5H5)(phosphine)2Ru(SnX3)] (X=F, Cl, Br): ligand effect

✍ Scribed by Patricia A. Robles-Dutenhefner; Edmilson M. Moura; Gennaro J. Gama; Helmuth G.L. Siebald; Elena V. Gusevskaya


Book ID
104421000
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
166 KB
Volume
164
Category
Article
ISSN
1381-1169

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Synthesis of acetic acid from methanol a
✍ Hisahiro Einaga; Tetsu Yamakawa; Sumio Shinoda 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 545 KB

## Catalytic activity of [ ( $-C5Hs) (PPh,),RuX] (X = Cl ( 1), SnF, (2) ) was investigated for the highly selective formation of methyl acetate with methanol used as the sole source. Complex 2 was found to be more catalytically active than the singlemetallic complex 1. For both complexes, the init