✦ LIBER ✦

Synthesis of methyl 5-O-acetyl-7-deoxy-2,3-O-isopropylidene-heptofuranosid-6-uloses

✍ Scribed by Allan R. Moorman; Ronald T. Borchardt

Publisher: Elsevier Science
Year: 1983
Tongue: English
Weight: 223 KB
Volume: 119
Category: Article
ISSN: 0008-6215
DOI: 10.1016/0008-6215(83)84064-6

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis, crystal structure, and confor

Synthesis, crystal structure, and conformation of methyl 6-deoxy-2,3-O-isopropylidene-α-d-manno-heptofuranoside

✍ Janusz W. Krajewski; Przemysa̵w Gluziński; Zbigniew Pakulski; Aleksander Zamojsk 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 531 KB

Methyl 6-deoxy-2,3-0-isopropylidene-a-D-manno-heptofuranoside (9) has been synthesised from the acetyliron complex 2 by a sequence of reactions involving deprotonation of 2, its reaction with aldehyde 5, decomplexation, isolation of 7, and reduction to 9. Compound 9 crystallises in the orthorbombic

Synthesis of 5-deoxy-5-C-(diphenylphosph

Synthesis of 5-deoxy-5-C-(diphenylphosphinyl)-1,2-O-isopropylidene-3-O-methyl-β-l-idofuranose

✍ Manabu Yamada; Mitsuji Yamashita; Saburo Inokawa 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 155 KB

Synthesis of 1,2,4-tri-O-acetyl-6-deoxy-

Synthesis of 1,2,4-tri-O-acetyl-6-deoxy-6-C-(isopropylphosphinyl)-3,5-di-O-methyl-d-glucoseptanose and 1,2,4-tri-O-acetyl-3-O-benzyl-6-C-(butylphosphinyl)-6-deoxy-5-O-methyl-d-glucoseptanose

✍ Kuniaki Seo 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 384 KB

X-ray and conformational investigation o

X-ray and conformational investigation of 6-deoxy-6-C-(1,5-di-O-acetyl-2,3-O-isopropylidene-β-d-allo-pentofuranos-5-yl)-1,2:3,4-di-O-isopropylidene- α-d-galactopyranose and 6-C-(benzyl 5-deoxy-2,3-O-isopropylidene-β-d-ribofuranosid-5-yl)-1,2:3,4-di-O-isopropylidene- d-glycero-α-d-galacto-hexopyranose

✍ Janusz W. Krajewski; Wojciech Karpiesiuk; Anna Banaszek 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 523 KB

The structures of the title compounds (2b and 3) have been investigated in the solid state by X-ray methods. The crystals of 2b are monoclinic, space group P2,, and of 3 orthorhombit, space grtup P2,2,2,. The cell dimensions are: for 2b, a = 9.910(2), b = 11;745W, c = 11.810(3) A, /3 = 97.32(l)"; a

Synthesis, crystal structure, and confor

Synthesis, crystal structure, and conformation of 3-O-(6-O-acetyl-2,3-anhydro-4-deoxy-α-l-ribo-hexopyranosyl)-1,2:5,6-di-O-isopropylidene-α-d-glucofuranose

✍ Janusz W. Krajewski; Przemysław Gluziński; Zofia Urbańczyk-Lipkowska; Anna Banas 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 638 KB

3-0-(6-0-Acetyl-2,3-anhydro-4-deoxy-a-L-ribo-hexopyranosyl)-l,2:5,6-di-O-isopropylidene-a-D-glucofuranose has been synthesised and its monocrystal investigated by X-ray diffraction methods. The compound crystallises in the orthorhombic system, space group P2,2,2t, with cell constants a = 8.790( 7),

Stereospecific addition of a phosphinate

Stereospecific addition of a phosphinate and of phosphonates to methyl 6-deoxy-2,3-O-isopropylidene-α-L-lyxo-hexopyranosid-4-ulose

✍ Pham Thanh Long; Mitsuji Yamashita; Saburo Inokawa 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 193 KB

As an alternative method for preparing sugar derivatives having a phosphorus atom as the ring heteroatom', attempts to introduce a carbon-phosphorus bond were made by using the addition reaction of phosphorus compounds to glycosiduloses. It is known that reaction of carbonyl compounds with dialkyl p