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Synthesis of methyl 4,6-O-benzylidene-2,3-dideoxy-2-C-formyl-α-d-erythro-hex-2-enopyranoside

✍ Scribed by María I. Mangione; Alejandra G. Suárez; Rolando A. Spanevello

Book ID: 111712680
Publisher: Elsevier Science
Year: 2005
Tongue: English
Weight: 278 KB
Volume: 340
Category: Article
ISSN: 0008-6215
DOI: 10.1016/j.carres.2004.10.018

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## Abstract Die Methyl‐4,6‐__O__‐benzyliden‐2,3‐di‐__O__‐methylhexopyranoside mit D‐__gluco__‐ (**1**), D‐__altro__‐ (**3**) und D‐__allo__‐Konfiguration (**4**) reagieren mit n‐Butyllithium unter Methanol‐Eliminierung zu Methyl‐4,6‐__O__‐benzyliden‐3‐desoxy‐2‐__O__‐methyl‐α‐D‐__erythro__‐hex‐2‐eno