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Improved Synthesis of Methyl 4,6-O-Benzylidene-3-cyano-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside and Methyl 4,6-O-Benzylidene-2,3-dideoxy-3-C-formyl-α-D-erythro-hex-2-enopyranoside

✍ Scribed by Spanevello, Rolando A.; Pellegrinet, Silvina C.

Book ID: 127287259
Publisher: Taylor and Francis Group
Year: 1995
Tongue: English
Weight: 327 KB
Volume: 25
Category: Article
ISSN: 0039-7911
DOI: 10.1080/00397919508015503

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## Abstract Die Methyl‐4,6‐__O__‐benzyliden‐2,3‐di‐__O__‐methylhexopyranoside mit D‐__gluco__‐ (**1**), D‐__altro__‐ (**3**) und D‐__allo__‐Konfiguration (**4**) reagieren mit n‐Butyllithium unter Methanol‐Eliminierung zu Methyl‐4,6‐__O__‐benzyliden‐3‐desoxy‐2‐__O__‐methyl‐α‐D‐__erythro__‐hex‐2‐eno