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Synthesis of Metal-Boron Coordination Compounds by Oxidative Addition

✍ Scribed by Dr. G. Schmid; Dipl.-Chem W. Petz; Dipl.-Chem W. Arloth; Prof. Dr. H. Nöth


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
208 KB
Volume
6
Category
Article
ISSN
0044-8249

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Oxidative Addition of Boron Trifluoride
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from a benzene solution at room temperature. 1 H NMR (400.1 MHz, C 6 D 6 ): d = 2.71À2.60 (m, 6 H, Cy), 2.23À2.15 (m, 12 H, Cy), 1.81À1.20 (m, 48 H, Cy); 11 B{ 1 H} NMR (128.4 MHz, C 6 D 6 ): d = 30 ppm; 13 C{ 1 H} NMR (100.6 MHz, C 6 D 6 ): d = 35.8 (vt, N =j 1 J P-C + 3 J P-C j= 28 Hz, C 1 Cy), 30

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The addition of organocerium reagents 2a-g to phosphinoyl benzyl group bound to the carbonyl moiety should be metallated. The latter reaction is the first reported synthesis chloride 1a or chlorophosphates 1b leads to the synthesis of phosphane oxides 3aa-ag and phosphonates 3bb, be in good of β-oxo