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Synthesis of Medium Ring Nitrogen Heterocycles via a Tandem Copper-Catalyzed C−N Bond Formation−Ring-Expansion Process

✍ Scribed by Klapars, Artis; Parris, Sean; Anderson, Kevin W.; Buchwald, Stephen L.


Book ID
111652623
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
88 KB
Volume
126
Category
Article
ISSN
0002-7863

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ChemInform Abstract: Synthesis of Medium
✍ R. C. LAROCK; C. TU; P. PACE 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 35 KB 👁 2 views

Synthesis of Medium-Ring Nitrogen Heterocycles via Palladium-Catalyzed Heteroannulation of 1,2-Dienes. -The Pd-catalyzed reaction of allenes with both aryl and vinyl iodides bearing amine functionalities offers a useful new route to medium-ring nitrogen heterocycles. Seven-membered rings are formed