Synthesis of maleate derivatives in isocyanide-base MCRs: reaction of 2-mercaptobenzoxazole with alkyl isocyanides and dialkyl acetylenedicarboxylates
โ Scribed by Khandan-Barani, Khatereh; Maghsoodlou, Malek Taher; Hassanabadi, Alireza; Hosseini-Tabatabaei, Mohammad Reza; Saffari, Jilla; Kangani, Mehrnoosh
- Book ID
- 125368637
- Publisher
- Springer Netherlands
- Year
- 2013
- Tongue
- English
- Weight
- 244 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0922-6168
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## Abstract For Abstract see ChemInform Abstract in Full Text.
The highly reactive 1:1 intermediate generated in the reaction between an alkyl isocyanide and a dialkyl acetylenedicarboxylate is trapped by N-alkyl isatin to yield iminolactones in fairly high yields.