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Reaction between alkyl isocyanides and dialkyl acetylenedicarboxylates in the presence of N-alkyl isatins: convenient synthesis of γ-spiro-iminolactones

✍ Scribed by Abbas Ali Esmaeili; Masoomeh Darbanian

Book ID: 104205460
Publisher: Elsevier Science
Year: 2003
Tongue: French
Weight: 109 KB
Volume: 59
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(03)00809-3

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✦ Synopsis

The highly reactive 1:1 intermediate generated in the reaction between an alkyl isocyanide and a dialkyl acetylenedicarboxylate is trapped by N-alkyl isatin to yield iminolactones in fairly high yields.

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