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Synthesis of macrocycles via allylic radical intermediates. A total synthesis of (−)-zearalenone

✍ Scribed by Stephen A Hitchcock; Gerald Pattenden

Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
218 KB
Volume
31
Category
Article
ISSN
0040-4039

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✦ Synopsis

A concise synthesis of optical1 active (-)-zearalenone (1) which uses a novel 14-u trig macrocyc isatlon from an allylic radical r intermediate (Scheme 1) as a key feature, is described.

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