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Synthesis of low-molecular-weight telechelic polyisobutylene

✍ Scribed by E. Walch; R.J. Gaymans


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
579 KB
Volume
34
Category
Article
ISSN
0032-3861

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πŸ“œ SIMILAR VOLUMES


Investigation of the structure and prope
✍ Don Loveday; Garth L. Wilkes; Youngkwan Lee; Robson F. Storey πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 251 KB πŸ‘ 2 views

The solid state morphology of recently developed sulfonated polyisobutylene (PIB) telechelic ionomers with narrow molecular weight distribution (MWD) ( M V w /M V n Γ‰ 1.15) was investigated. A small angle X-ray scattering (SAXS) peak often associated with the aggregation of the ionic species in the

Synthesis of isobutenyl-telechelic polyi
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Isobutenyl-telechelic polyisobutylenes (PIBs) were synthesized by reacting tert-chlorine-telechelic and living PIBs with isobutenyltrimethylsilane (IBTMS) in the presence of TIC14 in CH2Cl2/hexane (40/60 v/v) solvent mixtures at -78Β°C. In order to obtain PIB oligomers, living polymerization of isobu

Investigation of the structure and prope
✍ Don Loveday; Garth L. Wilkes; Youngkwan Lee; Robson F. Storey πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 251 KB πŸ‘ 2 views

Sulfonated polyisobutylene (PIB) telechelic ionomers with narrow molecular weight distribution (MWD) have been recently developed, providing additional control over the structure and properties of these novel polymers. A small angle X-ray scattering (SAXS) peak often associated with the aggregation

The use of different diols in the synthe
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The synthesis of low-molecular-weight (M V w (GPC) Γ΅ 72000 g mol) lactic- acid-based telechelic prepolymers by condensation polymerization of L-lactic acid was investigated. All polymerizations were carried out in the melt, using tin(II)octoate as catalyst, different diols, and different polymerizat

Molecular weight dependence of stress re
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Stress relaxation measurements in simple exten6ion of three commercial samples of polyisobutylene (PIB) of different viscosity molecular weights (1.1, 1.7 and 2.3 x 106) have been made at stretch ratios (,~) up to about 2. Data obtained at 3 Β° and 50 Β° have been reduced at 25 Β°. As already found pre