The solid state morphology of recently developed sulfonated polyisobutylene (PIB) telechelic ionomers with narrow molecular weight distribution (MWD) ( M V w /M V n Γ 1.15) was investigated. A small angle X-ray scattering (SAXS) peak often associated with the aggregation of the ionic species in the
Synthesis of low-molecular-weight telechelic polyisobutylene
β Scribed by E. Walch; R.J. Gaymans
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 579 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0032-3861
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Isobutenyl-telechelic polyisobutylenes (PIBs) were synthesized by reacting tert-chlorine-telechelic and living PIBs with isobutenyltrimethylsilane (IBTMS) in the presence of TIC14 in CH2Cl2/hexane (40/60 v/v) solvent mixtures at -78Β°C. In order to obtain PIB oligomers, living polymerization of isobu
Sulfonated polyisobutylene (PIB) telechelic ionomers with narrow molecular weight distribution (MWD) have been recently developed, providing additional control over the structure and properties of these novel polymers. A small angle X-ray scattering (SAXS) peak often associated with the aggregation
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