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Synthesis of Long-Chain Sugars by Iterative, Diastereoselective Homologation of 2,3-O-Isopropylidene-D-glyceraldehyde with 2-Trimethylsilylthiazole

โœ Scribed by Prof. Dr. Alessandro Dondoni; Dr. Giancarlo Fantin; Dr. Marco Fogagnolo; Dr. Alessandro Medici


Book ID
101554578
Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
376 KB
Volume
25
Category
Article
ISSN
0044-8249

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1,3-Dipolar Cycloadditions of N-Benzyl-2
โœ Branislav Dugoviฤ; Lubor Fiลกera; Hans-Ulrich ReiรŸig ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 189 KB

## Abstract The siteselectivity of cycloadditions of the Dโ€glyceraldehydeโ€derived nitrone **1** and methoxyallene (**2**) is strongly influenced by Lewis acids. The uncatalyzed reaction results in the formation of isomeric isoxazolidines **3a**โ€“**3d** and **4a**โ€“**4c**, whereas in the presence of d