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ChemInform Abstract: Synthesis of C-Glycosyl Isoxazoles and Branched-Chain Enuloses from 2,3-O-Isopropylidene-D-glyceraldehyde.

✍ Scribed by J. M. Banez Sanz; J. A. Lopez Sastre; M. R. Patino Molina; C. Romero-Avila Garcia


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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Nucleophilic Additions of Grignard Reagents to N-Benzyl-2,3-O-isopropylidene-D-glyceraldehyde Nitrone (BIGN). Synthesis of (2S,3R) and (2S,3S)-3-Phenylisoserine. -The addition of Grignard reagents to the nitrone (I) proceeds with high anti or syn selectivity depending on the Lewis acid used. The re