Synthesis of Lithium 1-Alkynesulfenates by the Mild Oxidation of Thiolates with a Pinacolone-Derived N-Sulfonyloxaziridine.
β Scribed by Franck Sandrinelli; Cedric Boudou; Caroline Caupene; Marie-Therese Averbuch-Pouchot; Stephane Perrio; Patrick Metzner
- Book ID
- 102000736
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 21 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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The synthesis of 2,5,l-benzoxazasilepines 3 or the benzoxazasilaspiro compound 4, has been achieved by the reaction of o-lithio-N-(2-1ithiooxyethyl)-N-methyl-aniline (2) with R2SiC12 (R = Me, Et, Ph) or SiCI 4, respectively. The reaction led to the formation of cyclic products, even under conditions
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