The reaction mechanisms during calcination of a Li,CO,/Co,O, mixture in air and CO, were monitored by thermogravimetry, differential thermal analysis and complementary calcinations at 300 and 500ยฐC. It was determined how weight reduction, specific surface area and the formation of phases develop. Be
โฆ LIBER โฆ
Synthesis of LiCoO2 starting from carbonate precursors II. Influence of calcination conditions and leaching
โ Scribed by Anders Lundblad; Bill Bergman
- Book ID
- 104296581
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- English
- Weight
- 939 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0167-2738
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โฆ Synopsis
The effect of initial Li:Co ratio, calcination atmosphere, temperature, leaching in H,O or acetic acid solution on reaction completeness, final Li:Co ratio, primary particle size, conductivity and its sensitivity to different atmospheres has been investigated. The calcination gas composition was found to be very important. A powder with a primary particle size of 100-300 nm and with less than 3 wt.% of unreacted Li,CO, was obtained.
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