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Synthesis of Large Polycyclic Aromatic Hydrocarbons: Variation of Size and Periphery

✍ Scribed by Dötz, Florian; Brand, Johann Diedrich; Ito, Shunji; Gherghel, Lileta; Müllen, Klaus

Book ID
115499045
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
299 KB
Volume
122
Category
Article
ISSN
0002-7863

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The formation of cyclopenta[cd]pyrene (5) and benzo[ghi]fluoranthene (6) upon FVT of 3,9bisethynylphenanthrene (1) and 8-ethynylfluoranthene (2), respectively, suggests that redundant ethynyl substituents, which cannot give five-and/or six-membered ring formation via ethynyl ethylidene carbene equil