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Synthesis of l-2-spirocyclopropyl-2-deoxyarabinose

✍ Scribed by Russell C. Petter; David G. Powers


Book ID
104232721
Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
270 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis


The synthesis of L-2-spirocyclopropyl-2-deoxyarabinose from L-arabinose is described. Unusual reactions of a dichlorocyclopropane intermediate are observed. The target compounds may serve as mechanism-based inactivators of/?-galactosidase.

Cell surface carbohydrates mediate cell-to-cell communication and the "social behavior" of


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