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Synthesis of isoquinolines by cycloaddition of arynes to 1,2,4-triazines

✍ Scribed by António M.d'A.Rocha Gonsalves; Teresa M.V.D. Pinho e Melo; Thomas L. Gilchrist

Book ID
104204996
Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
509 KB
Volume
48
Category
Article
ISSN
0040-4020

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✦ Synopsis

Absfmct: Benxyne has been generated from benzencdiezonimn-2carboxylate in the presence of several 1,2,4triaxinea 1 snd isoquinolines 2 have been is&ted ia inodeam yield. I-Aminobenarkole was also used as the scurce of benxyne and kxpinolines went again is&ted in mode&e yield from these react&s CMe&ykuyne, which was generated from 5-methybhranilic acid, reacted unselectively with the trkines to give mixtmes of d and 7-methylisaquinolines 3 and 4 On the ok hand reactions of 3-methylbenzyne with the hiazines Id aid le promded

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