Synthesis of isoquinoline alkaloids - III pilocereine and “isopilocereine”

✍ Scribed by J.M. Bobbitt; R. Ebermann; Marcelle Schubert

• Publisher: Elsevier Science
• Year: 1963
• Tongue: French
• Weight: 136 KB
• Volume: 4
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)90676-8

✦ Synopsis

TBn nLEX_CLvo, pilocereine,4*5 II, and piloceredine,6 are postulated6 to arise from the oxiaatlve condensation of lophocerine, I. 6 We have previously synthesized I.7 !Je aox wish to report that I has been converted to a col-zple:: mixture containing "isopi3.0cereine",8 III, pilocereine, II, and probably piloceredine9 by a-zi.;l&ion with potassium ferricyanide in an amoniu? acetate buffer (@-I 6.0). The reaction is based upon the elegant, but relative_ellF